Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP
Identifieur interne : 004627 ( Main/Exploration ); précédent : 004626; suivant : 004628Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP
Auteurs : Dingcai Wu [République populaire de Chine, États-Unis] ; Zhenghui Li [République populaire de Chine] ; Mingjiang Zhong [États-Unis] ; Tomasz Kowalewski [États-Unis] ; Krzysztof Matyjaszewski [États-Unis]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2014-04-07.
Abstract
A facile templated synthesis of functional nanocarbon materials with well‐defined spherical mesopores is developed using all‐organic porogenic precursors comprised of hairy nanoparticles with nitrogen‐rich polyacrylonitrile shells grafted from sacrificial cross‐linked poly(methyl methacrylate) cores (xPMMA‐g‐PAN). Such shape‐persistent all‐organic nanostructured precursors, prepared using atom transfer radical polymerization (ATRP), assure robust formation of template nanostructures with continuous PAN precursor matrix over wide range of compositions, and allow for removal of the sacrificial template through simple thermal decomposition. Carbon materials prepared using this method combine nitrogen enrichment with hierarchical nanostructure comprised of microporous carbon matrix interspersed with mesopores originating from sacrificial xPMMA cores, and thus perform well as CO2 adsorbents and as supercapacitor electrodes.
Url:
DOI: 10.1002/ange.201309836
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 003170
- to stream Istex, to step Curation: 003170
- to stream Istex, to step Checkpoint: 000130
- to stream Main, to step Merge: 004859
- to stream Main, to step Curation: 004627
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP</title><author><name sortKey="Wu, Dingcai" sort="Wu, Dingcai" uniqKey="Wu D" first="Dingcai" last="Wu">Dingcai Wu</name></author><author><name sortKey="Li, Zhenghui" sort="Li, Zhenghui" uniqKey="Li Z" first="Zhenghui" last="Li">Zhenghui Li</name></author><author><name sortKey="Zhong, Mingjiang" sort="Zhong, Mingjiang" uniqKey="Zhong M" first="Mingjiang" last="Zhong">Mingjiang Zhong</name></author><author><name sortKey="Kowalewski, Tomasz" sort="Kowalewski, Tomasz" uniqKey="Kowalewski T" first="Tomasz" last="Kowalewski">Tomasz Kowalewski</name></author><author><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:D07FFE332FE902C65224F9B22F8655AAE6FD68F5</idno><date when="2014" year="2014">2014</date><idno type="doi">10.1002/ange.201309836</idno><idno type="url">https://api.istex.fr/document/D07FFE332FE902C65224F9B22F8655AAE6FD68F5/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">003170</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">003170</idno><idno type="wicri:Area/Istex/Curation">003170</idno><idno type="wicri:Area/Istex/Checkpoint">000130</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000130</idno><idno type="wicri:doubleKey">0044-8249:2014:Wu D:templated:synthesis:of</idno><idno type="wicri:Area/Main/Merge">004859</idno><idno type="wicri:Area/Main/Curation">004627</idno><idno type="wicri:Area/Main/Exploration">004627</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP<ref type="note" target="#nss"></ref></title><author><name sortKey="Wu, Dingcai" sort="Wu, Dingcai" uniqKey="Wu D" first="Dingcai" last="Wu">Dingcai Wu</name><affiliation wicri:level="1"><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat‐sen University</wicri:regionArea><wicri:noRegion>Sun Yat‐sen University</wicri:noRegion></affiliation><affiliation wicri:level="1"><country wicri:rule="url">République populaire de Chine</country></affiliation><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><placeName><region type="state">Pennsylvanie</region></placeName><wicri:cityArea>Dingcai Wu, Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat‐sen University, Guangzhou 510275 (China)===Tomasz Kowalewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213 (USA)===Krzysztof Matyjaszewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:cityArea></affiliation></author><author><name sortKey="Li, Zhenghui" sort="Li, Zhenghui" uniqKey="Li Z" first="Zhenghui" last="Li">Zhenghui Li</name><affiliation wicri:level="1"><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat‐sen University</wicri:regionArea><wicri:noRegion>Sun Yat‐sen University</wicri:noRegion></affiliation></author><author><name sortKey="Zhong, Mingjiang" sort="Zhong, Mingjiang" uniqKey="Zhong M" first="Mingjiang" last="Zhong">Mingjiang Zhong</name><affiliation wicri:level="4"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:regionArea><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region><settlement type="city">Pittsburgh</settlement></placeName><orgName type="university">Université Carnegie-Mellon</orgName></affiliation></author><author><name sortKey="Kowalewski, Tomasz" sort="Kowalewski, Tomasz" uniqKey="Kowalewski T" first="Tomasz" last="Kowalewski">Tomasz Kowalewski</name><affiliation wicri:level="4"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:regionArea><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region><settlement type="city">Pittsburgh</settlement></placeName><orgName type="university">Université Carnegie-Mellon</orgName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><placeName><region type="state">Pennsylvanie</region></placeName><wicri:cityArea>Dingcai Wu, Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat‐sen University, Guangzhou 510275 (China)===Tomasz Kowalewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213 (USA)===Krzysztof Matyjaszewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:cityArea></affiliation></author><author><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><affiliation wicri:level="4"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:regionArea><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region><settlement type="city">Pittsburgh</settlement></placeName><orgName type="university">Université Carnegie-Mellon</orgName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><placeName><region type="state">Pennsylvanie</region></placeName><wicri:cityArea>Dingcai Wu, Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat‐sen University, Guangzhou 510275 (China)===Tomasz Kowalewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213 (USA)===Krzysztof Matyjaszewski, Department of Chemistry, Carnegie Mellon University, Pittsburgh</wicri:cityArea></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie</title><title level="j" type="alt">ANGEWANDTE CHEMIE</title><idno type="ISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><imprint><biblScope unit="vol">126</biblScope><biblScope unit="issue">15</biblScope><biblScope unit="page" from="4038">4038</biblScope><biblScope unit="page" to="4041">4041</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2014-04-07">2014-04-07</date></imprint><idno type="ISSN">0044-8249</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-8249</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A facile templated synthesis of functional nanocarbon materials with well‐defined spherical mesopores is developed using all‐organic porogenic precursors comprised of hairy nanoparticles with nitrogen‐rich polyacrylonitrile shells grafted from sacrificial cross‐linked poly(methyl methacrylate) cores (xPMMA‐g‐PAN). Such shape‐persistent all‐organic nanostructured precursors, prepared using atom transfer radical polymerization (ATRP), assure robust formation of template nanostructures with continuous PAN precursor matrix over wide range of compositions, and allow for removal of the sacrificial template through simple thermal decomposition. Carbon materials prepared using this method combine nitrogen enrichment with hierarchical nanostructure comprised of microporous carbon matrix interspersed with mesopores originating from sacrificial xPMMA cores, and thus perform well as CO2 adsorbents and as supercapacitor electrodes.</div></front></TEI><affiliations><list><country><li>République populaire de Chine</li><li>États-Unis</li></country><region><li>Pennsylvanie</li></region><settlement><li>Pittsburgh</li></settlement><orgName><li>Université Carnegie-Mellon</li></orgName></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Wu, Dingcai" sort="Wu, Dingcai" uniqKey="Wu D" first="Dingcai" last="Wu">Dingcai Wu</name></noRegion><name sortKey="Li, Zhenghui" sort="Li, Zhenghui" uniqKey="Li Z" first="Zhenghui" last="Li">Zhenghui Li</name><name sortKey="Wu, Dingcai" sort="Wu, Dingcai" uniqKey="Wu D" first="Dingcai" last="Wu">Dingcai Wu</name></country><country name="États-Unis"><region name="Pennsylvanie"><name sortKey="Wu, Dingcai" sort="Wu, Dingcai" uniqKey="Wu D" first="Dingcai" last="Wu">Dingcai Wu</name></region><name sortKey="Kowalewski, Tomasz" sort="Kowalewski, Tomasz" uniqKey="Kowalewski T" first="Tomasz" last="Kowalewski">Tomasz Kowalewski</name><name sortKey="Kowalewski, Tomasz" sort="Kowalewski, Tomasz" uniqKey="Kowalewski T" first="Tomasz" last="Kowalewski">Tomasz Kowalewski</name><name sortKey="Kowalewski, Tomasz" sort="Kowalewski, Tomasz" uniqKey="Kowalewski T" first="Tomasz" last="Kowalewski">Tomasz Kowalewski</name><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><name sortKey="Zhong, Mingjiang" sort="Zhong, Mingjiang" uniqKey="Zhong M" first="Mingjiang" last="Zhong">Mingjiang Zhong</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Amérique/explor/PittsburghV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 004627 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 004627 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Amérique
|area= PittsburghV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:D07FFE332FE902C65224F9B22F8655AAE6FD68F5
|texte= Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP
}}
| This area was generated with Dilib version V0.6.38. |  |